Question #45019

NO2 + H2O -> HNO3 + NO
How many grams of nitrogen dioxide are required in this reaction to produce 5.00 g HNO3?

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Answer on Question #45019 – Chemistry – Other

Question

NO2+H2OHNO3+NO\mathrm{NO_2} + \mathrm{H_2O} \rightarrow \mathrm{HNO_3} + \mathrm{NO}


How many grams of nitrogen dioxide are required in this reaction to produce 5.00 g HNO₃?

Solution

Molar mass of NO2\mathrm{NO_2}: M(NO2)=46.01 g/mol\mathrm{M}(\mathrm{NO_2}) = 46.01\ \mathrm{g/mol}

Molar mass of HNO3\mathrm{HNO_3}: M(HNO3)=63.01 g/mol\mathrm{M}(\mathrm{HNO_3}) = 63.01\ \mathrm{g/mol}

Balanced chemical equation is


3NO2+H2O2HNO3+NO3 \mathrm{NO_2} + \mathrm{H_2O} \rightarrow 2 \mathrm{HNO_3} + \mathrm{NO}


As is clear from the balanced chemical equation, 3 mol of NO2\mathrm{NO_2} are required to produce 2 mol of HNO3\mathrm{HNO_3}. Thus, we can write the proportion


2M(HNO3)3M(NO2)2 \cdot \mathrm{M}(\mathrm{HNO_3}) - 3 \cdot \mathrm{M}(\mathrm{NO_2})m(HNO3)m(NO2)\mathrm{m}(\mathrm{HNO_3}) - \mathrm{m}(\mathrm{NO_2})m(NO2)=3M(NO2)m(HNO3)/2M(HNO3)=346.015.00/263.0=5.48 g\mathrm{m}(\mathrm{NO_2}) = 3 \cdot \mathrm{M}(\mathrm{NO_2}) \cdot \mathrm{m}(\mathrm{HNO_3}) / 2 \cdot \mathrm{M}(\mathrm{HNO_3}) = 3 \cdot 46.01 \cdot 5.00 / 2 \cdot 63.0 = 5.48\ \mathrm{g}


Answer: 5.48 g of nitrogen dioxide are required to produce 5.00 g HNO₃


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