Question #42379

a quantity of chlorine gas occupies a volume of 50L at 27c and 721kPa. how many gram of chlorine gas are present

Expert's answer

Answer on Question #42379 - Chemistry - Other

Question:

A quantity of chlorine gas occupies a volume of 50L at 27c and 721kPa. How many gram of chlorine gas are present?

Answer:

The ideal gas law is:


PV=nRTPV = nRT


where PP is the absolute pressure of the gas, VV is the volume of the gas, nn is the amount of substance of gas (measured in moles), RR is the ideal, or universal, gas constant, and TT is the absolute temperature of the gas.

Absolute pressure of chlorine gas equals:


P=721kPa=721000PaP = 721\,kPa = 721000\,Pa


Volume of chlorine gas equals:


V=50L=5102m3V = 50\,L = 5 \cdot 10^{-2}\,m^3


Absolute temperature of chlorine gas is:


T = 27\,^{\circ}\mathrm{C} = 300\,K


That's why the number of moles of chlorine gas is:


n=PVRT=72100051028.314300=14.45moln = \frac{PV}{RT} = \frac{721000 \cdot 5 \cdot 10^{-2}}{8.314 \cdot 300} = 14.45\,mol


Mass of chlorine gas equals:


m=nMm = n \cdot M


where MM is the molar mass of chlorine gas, M=71g/molM = 71\,g/mol.

So the mass of 14.45 mol of chlorine gas equals:


m=14.4571=1025.95gm = 14.45 \cdot 71 = 1025.95\,g


Answer: m(Cl2)=1025.95gm(\mathrm{Cl}_2) = 1025.95\,g

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