A sample of O2 was collected over water at 23˚C and 760 torr. What is the partial pressure O2 at the given temperature and pressure? The vapor pressure of water at 23˚C is 21.2 torr.
Solution:
Dalton's law can be used: "the total pressure exerted by a mixture of gases is equal to the sum of the partial pressures of the gases in the mixture".
This is shown by the equation:
Ptotal = P1 + P2 + ... + Pn
Ptotal = 760 torr
Poxygen = unknown
Pwater = 21.2 torr
Thus,
Poxygen = Ptotal − Pwater = 760 torr − 21.2 torr = 738.8 torr
Poxygen = 738.8 torr
Answer: The partial pressure O2 is 738.8 torr
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