if a 0.22560g of sodium bicarbonate is titrated with 0.1165N sulphuric acid. what volume of acid is required to reach the end point?
Solution:
sodium bicarbonate = NaHCO3
sulphuric acid = H2SO4
Calculate the moles of sodium bicarbonate (NaHCO3):
The molar mass of NaHCO3 is 84.007 g/mol
Therefore,
(0.22560 g NaHCO3) × (1 mol NaHCO3 / 84.007 g NaHCO3) = 0.0026855 mol NaHCO3
Balanced chemical equation:
2NaHCO3 + H2SO4 → Na2SO4 + 2H2O + 2CO2
According to stoichiometry:
Moles of NaHCO3 = 2 × Moles of H2SO4
OR:
Moles of NaHCO3 = Normality of H2SO4 × Volume of H2SO4
Therefore,
Volume of H2SO4 = Moles of NaHCO3 / Normality of H2SO4
Volume of H2SO4 = (0.0026855 mol) / (0.1165 N) = 0.02305 L = 23.05 mL
Volume of H2SO4 = 23.05 mL
Answer: 23.05 mL of H2SO4 is required to reach the end point
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