For each of the following compounds, draw its isomeric pair that represents a chain, positional and functional group isomerism:
a) CH3CH2CH=CH3
b) CH3CH(CH3)CH(CH3)CH3
c) CH3CH2CH2CH2CH2OH
d) CH3CH2COOH
e) CH2CH2CHO
Solution:
Chain isomerism: These isomers arise because of the possibility of branching in carbon chains.
Position isomerism: In position isomerism, the basic carbon skeleton remains unchanged, but important groups are moved around on that skeleton.
Functional group isomerism: In this variety of structural isomerism, the isomers contain different functional groups - that is, they belong to different families of compounds (different homologous series).
a) CH3CH2CH=CH3
b) CH3CH(CH3)CH(CH3)CH3
с) CH3CH2CH2CH2CH2OH
d) CH3CH2COOH
e) CH2=CH2CHO
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