Hydrogen is prepared commercially by the reaction of methane and water vapor at elevated temperatures.
CH4 (g) + H2O (g) ⇌ H2 (g) + CO (g)
What is the equilibrium constant for the reaction if a mixture at equilibrium contains gases with the following concentrations, at a temperature of 760 °C?
CH4 = 0.126 M
H2O = 0.242 M
CO = 0.126 M
H2 = 1.15 M
[CH4]Â = 0.126 M
[H2O] = 0.242 M
[CO] = 0.126 M
[H2]Â = 1.15 M
Solution:
Balanced chemical equation:
CH4(g) + H2O(g) ⇌ 3H2(g) + CO(g)
The equilibrium expression for the reaction system:
Kc = ([CO] × [H2]3) / ([H2O] × [CH4])
Kc = (0.126 × 1.153) / (0.242 × 0.126) = (0.19163) / (0.030492) = 6.28
Kc = 6.28 M2
Answer: The equilibrium constant (Kc) for the reaction is 6.28
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