4. A combustion reaction wherein 15.0 g of propane (C3H8) is burned with 75.0 g of oxygen (O2).
a. Determine the limiting reactant.
b. What is the maximum amount of CO2 (g) can you produce?.
Solution:
The molar mass of C3H8 is 44.1 g/mol
The molar mass of O2 is 32.0 g/mol
Calculate the number of moles of each reactant:
(15.0 g C3H8) × (1 mol C3H8 / 44.1 g C3H8) = 0.34 mol C3H8
(75.0 g O2) × (1 mol O2 / 32.0 g O2) = 2.34 mol O2
Balanced chemical equation:
C3H8(g) + 5O2(g) ⟶ 3CO2(g) + 4H2O(g)
According to stoichiometry:
1 mol of C3H8 reacts with 5 mol of O2
Thus, 0.34 mol of C3H8 reacts with:
(0.34 mol C3H8) × (5 mol O2 / 1 mol C3H8) = 1.7 mol O2
However, initially there is 2.34 mol of O2Â (according to the task).
Thus, C3H8Â acts as limiting reactant and O2Â is excess reactant.
According to stoichiometry:
1 mol of C3H8 produces 3 mol of CO2
Thus, 0.34 mol of C3H8 produces:
(0.34 mol C3H8) × (3 mol CO2 / 1 mol C3H8) = 1.02 mol CO2
The molar mass of CO2 is 44.01 g/mol
Hence,
(1.02 mol CO2) × (44.01 g CO2 / 1 mol CO2) = 44.89 g CO2
Answer:
a) The limiting reactant is propane (C3H8)
b) The maximum amount of CO2 is 1.02 mol (or 44.89 g)
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