1. Which of the following has the incorrect assignment of oxidation numbers?
a. Fe2O3 (Fe: 2+, O: 2-)
b. H2SO4 (H:1+, S: 6+, O: 2-)
c. Cr2O72- (Cr: 6+, O: 2-)
d. KCl (K: 1+, Cl: 1-)
2. Which of the following has the incorrect assignment of oxidation numbers?
a. H2O2 (H: 1+, O: 2-)
b. NO3– (N: 5+, O: 2-)
c. NO2 (N: 4+, O: 2-)
d. K3PO4: (K: 1+, P: 5+, O: 2-)
3. Which of the following has the incorrect assignment of oxidation numbers?
a. SiO2 (Si: 4+, O: 2-)
b. KNO2 (K: 1+, N: 3+, O: 2-)
c. HNO3 (H: 1+, N: 3+, O: 2-)
d. NH4Cl (N: 3-, H: 1+, Cl: 1-)
Solution:
(1) Which of the following has the incorrect assignment of oxidation numbers?
a) Fe2O3 (Fe: 2+, O: 2−) – incorrect. Fe2O3 (Fe: 3+, O: 2−) – correct
b) H2SO4 (H:1+, S: 6+, O: 2−) – correct
c) Cr2O72- (Cr: 6+, O: 2−) – correct
d) KCl (K: 1+, Cl: 1−) – correct
Answer (1):
a) Fe2O3 (Fe: 2+, O: 2−)
(2) Which of the following has the incorrect assignment of oxidation numbers?
a) H2O2 (H: 1+, O: 2−) – incorrect. H2O2 (H: 1+, O: 1−) – correct.
b) NO3– (N: 5+, O: 2−) – correct
c) NO2 (N: 4+, O: 2−) – correct
d) K3PO4: (K: 1+, P: 5+, O: 2−) – correct
Answer (2):
a) H2O2 (H: 1+, O: 2−)
(3) Which of the following has the incorrect assignment of oxidation numbers?
a) SiO2 (Si: 4+, O: 2−) – correct
b) KNO2 (K: 1+, N: 3+, O: 2−) – correct
c) HNO3 (H: 1+, N: 3+, O: 2−) – incorrect. HNO3 (H: 1+, N: 5+, O: 2−) – correct.
d) NH4Cl (N: 3-, H: 1+, Cl: 1−) – correct
Answer (3):
c) HNO3 (H: 1+, N: 3+, O: 2−)
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