Answer to Question #281283 in Chemistry for sukriti singh

Question

A piston cylinder system contains a liquid at 25°C with molar volume given by

V = 20.05 – 6.15 X 10-5 P + 3.7 X 10-8 P

2

- 4 X 10-9 P

3

,

where V is in cm3

/mol and P is in atm for Pressure between 0 and 1000 atm and

(

∂V

∂T)

p

= 0. 007 + 2. 1 × 10−5P (

Cm3

mol . K)

The one mole of liquid is compress at constant temperature of 25°C from 2 atm to 900

atm. Determine the work necessary (J/mol) to carry out this process and the change in its

internal energy.

Answer 1

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