25.00 mL of 6.00 M H2SO4 solution is diluted with water to a volume of 2.000L. What is the [H+] and [OH-] of the resulting solution?
Solution:
Convert mL to L:
(25.00 mL) × (1 L / 1000 mL) = 0.025 L
Calculate the concentration of the diluted H2SO4 solution:
(6.00 M H2SO4) × (0.025 L / 2.000 L) = 0.075 M
CM(H2SO4) = 0.075 M
H2SO4 is a strong acid which dissociates as follows:
H2SO4 → 2H+ + SO42-
Therefore,
[H+] = 2 × CM(H2SO4) = 2 × (0.075 M) = 0.15 M
[H+] = 0.15 M
Kw = [H+] × [OH-] = 1.0×10-14
Therefore,
[OH-] = Kw / [H+] = (1.0×10-14) / (0.15) = 6.67×10-14
[OH-] = 6.67×10-14 M
Answer:
[H+] = 0.15 M
[OH-] = 6.67×10-14 M
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