Write the balanced net ionic equation when the following solutions are mixed. If no precipitation reaction occurred, indicate “no precipitation”. Indicate the phase of the ion and/or molecule.
1. AgNO3 + CaCl2
2. Cu(NO3)2 + (NH4)3PO4
3. KOH + FeCl2
4. Li2CO3 + CaCl2
5. Na2SO4 + NH4I
Solution:
(1):
2AgNO3(aq) + CaCl2(aq) → 2AgCl(s) + Ca(NO3)2(aq)
2Ag+(aq) + 2NO3-(aq) + Ca2+(aq) + 2Cl-(aq) → 2AgCl(s) + Ca2+(aq) + 2NO3-(aq)
Net ionic equation: Ag+(aq) + Cl-(aq) → AgCl(s)
(2):
3Cu(NO3)2(aq) + 2(NH4)3PO4(aq) → Cu3(PO4)2(s) + 6NH4NO3(aq)
3Cu2+(aq) + 6NO3-(aq) + 6NH4+(aq) + 2PO43-(aq) → Cu3(PO4)2(s) + 6NH4+(aq) + 6NO3-(aq)
Net ionic equation: 3Cu2+(aq) + 2PO43-(aq) → Cu3(PO4)2(s)
(3):
2KOH(aq) + FeCl2(aq) → Fe(OH)2(s) + 2KCl(aq)
2K+(aq) + 2OH-(aq) + Fe2+(aq) + 2Cl-(aq) → Fe(OH)2(s) + 2K+(aq) + 2Cl-(aq)
Net ionic equation: 2OH-(aq) + Fe2+(aq) → Fe(OH)2(s)
(4):
Li2CO3(aq) + CaCl2(aq) → CaCO3(s) + 2LiCl(aq)
2Li+(aq) + CO32-(aq) + Ca2+(aq) + 2Cl-(aq) → CaCO3(s) + 2Li+(aq) + 2Cl-(aq)
Net ionic equation: CO32-(aq) + Ca2+(aq) → CaCO3(s)
(5):
Na2SO4(aq) + 2NH4I(aq) → (NH4)2SO4(aq) + 2NaI(aq)
2Na+(aq) + SO42-(aq) + 2NH4+(aq) + 2I-(aq) → 2NH4+(aq) + SO42-(aq) + 2Na+(aq) + 2I-(aq)
Net ionic equation: No precipitation
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