Liquid octane CH
3
CH
2
6
CH
3
will react with gaseous oxygen O
2
to produce gaseous carbon dioxide CO
2
and gaseous water H
2
O
. Suppose 1.14 g of octane is mixed with 7.1 g of oxygen. Calculate the maximum mass of carbon dioxide that could be produced by the chemical reaction. Round your answer to 3
significant digits.
Solution:
The molar mass of octane is 114 g/mol
The molar mass of O2 is 32 g/mol
Determine moles of each reactant:
(1.14 g octane) × (1 mol octane / 114 g octane) = 0.010 mol octane
(7.1 g O2) × (1 mol O2 / 32.00 g O2) = 0.222 mol O2
Balanced chemical equation:
2CH3(CH2)6CH3(l) + 25O2(g) → 16CO2(g) + 18H2O(g)
According to the chemical equation above:
2 mol of octane reacts with 25 mol of O2
Thus, 0.010 mol of octane reacts with:
(0.010 mol octane) × (25 mol O2 / 2 mol octane) = 0.125 mol O2
However, initially there is 0.222 mol of O2 (according to the task).
Therefore, octane acts as limiting reagent and O2 is excess reagent.
According to stoichiometry:
2 mol of octane produces 16 mol of CO2
Thus, 0.010 mol of octane produces:
(0.010 mol octane) × (16 mol CO2 / 2 mol octane) = 0.08 mol CO2
The molar mass of CO2 is 44 g/mol
Therefore,
(0.08 mol CO2) × (44 g CO2 / 1 mol CO2) = 3.52 g CO2
Answer: The mass of carbon dioxide (CO2) is 3.52 grams
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