Which of the following statements is(are) true for all voltaic (or galvanic) cells?
(I) Reduction occurs at the cathode.
(II) The anode gains mass during discharge (note: this means operation of the cell.)
III) The voltage is less than or equal to zero.
Solution:
(I) Reduction occurs at the cathode. - TRUE
(II) The anode gains mass during discharge. - FALSE.
At anode oxidation takes place which means electrons pass out to the solution in a electrochemical cell i.e. it corrodes the electrode or electrode experiences mass loss.
(III) The voltage is less than or equal to zero. - FALSE.
The voltage may also be positive/greater than zero which actually depends upon the species used in the electrochemical recation.
Thus, the correct answer is only (I).
Answer: Only (I)
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