A flask is first evacuated so that it contains no gas at all. Then, 2.2 g of CO2 is introduced into the flask. On warming to 22 °C, the gas exerts a pressure of 318 mm Hg. What is the volume of the flask?
P(CO2) = 318 mmHg
V(CO2) = unknown
m(CO2) = 2.2 g
R = 62.3637 L mmHg mol-1 K-1
T = 22°C = (22 + 273) = 295 K
Solution:
The molar mass of CO2 is 44 g/mol
Hence,
(2.2 g CO2) × (1 mol CO2 / 44 g CO2) = 0.05 mol CO2
n(CO2) = 0.05 mol
The ideal gas equation can be used.
The ideal gas equation can be expressed as:
PV = nRT
Rearranging the ideal gas equation gives:
V = nRT / P
Hence,
V(CO2) = (0.05 mol × 62.3637 L mmHg mol-1 K-1 × 295 K) / (318 mmHg) = 2.89 L = 2.9 L
V(CO2) = 2.9 L
V(flask) = V(CO2) = 2.9 L
Answer: The volume of the flask is 2.9 liters
Comments
Leave a comment