Which of the following sets of quantum numbers is not possible?
a) n = 4, l = 2, ml = 0
b) n = 2, l = 1, ml = -1
c) n = 1, l = 0, ml = 0
d) n = 3, l = 3, ml = -2
e) n = 3, l = 1, ml = 0
Solution:
The set of quantum numbers n = 3, l = 3, ml = -2 is not possible for an electron.
Since l can be zero or a positive integer less than (n−1).
For a given value of n = 3, the possible values of l are 0, 1 or 2.
Answer: d) n = 3, l = 3, ml = -2
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