Titanium tetrachloride, TiCl4, is prepared by the reac- tion below.
3TiO2(s) + 4C(s) + 6Cl2(g) ¡
3 TiCl4(g) + 2 CO2(g) + 2 CO(g)
What is the maximum mass of TiCl4 that can be obtained from 35 g TiO2, 45 g Cl2, and 11 g C?
Solution:
The molar mass of TiO2 is 79.866 g/mol
The molar mass of Cl2 is 70.9060 g/mol
The molar mass of C is 12.0107 g/mol
The molar mass of TiCl4 is 189.679 g/mol
Balanced chemical equation:
3TiO2(s) + 4C(s) + 6Cl2(g) ⟶ 3TiCl4(g) + 2CO2(g) + 2CO(g)
Calculate moles of each reactant:
(35 g TiO2) × (1 mol TiO2 / 79.866 g TiO2) = 0.4382 mol TiO2
(11 g C) × (1 mol C / 12.0107 g C) = 0.9159 mol C
(45 g Cl2) × (1 mol Cl2 / 70.9060 g Cl2) = 0.6346 mol Cl2
Calculate stoichiometry coefficients:
TiO2: (0.4382 mol / 3 ) = 0.146
C: (0.9159 mol / 4) = 0.229
Cl2: (0.6346 mol / 6) = 0.106
As 0.106 is lowest, Cl2 is limiting reagent and product will form according to number of moles of Cl2.
According to stoichiometry:
6 mol of Cl2 produces 3 mol of TiCl4
Thus, 0.6346 mol of Cl2 produces:
(0.6346 mol Cl2) × (3 mol TiCl4 / 6 mol Cl2) = 0.3173 mol TiCl4
Calculate the mass of TiCl4:
(0.3173 mol TiCl4) × (189.679 g TiCl4 / 1 mol TiCl4) = 60.185 g TiCl4 = 60.2 g TiCl4
Answer: 60.2 grams of TiCl4
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