An alloy of Co, Rh and Mn contains these elements in the atomic ratio of 2 : 5 : 2 , respectively. What is the mass of a sample of this alloy containing a total of 8.75 x 1021 atoms ?
Solution:
N(Co) : N(Rh) : N(Mn) = 2 : 5 : 2
Co: 2x
Rh: 5x
Mn: 2x
2x + 5x + 2x = 8.75×1021 atoms
9x = 8.75×1021 atoms
x = 9.72×1020 atoms
Hence,
N(Co) = 2x = 2 × 9.72×1020 atoms = 1.95×1021 atoms
N(Rh) = 5x = 5 × 9.72×1020 atoms = 4.86×1021 atoms
N(Mn) = 2x = 2 × 9.72×1020 atoms = 1.95×1021 atoms
One mole of any substance contains 6.022×1023 atoms/molecules.
Hence,
n(Co) = (1.95×1021 atoms) × (1 mol / 6.022×1023 atoms) = 0.00324 mol
n(Rh) = (4.86×1021 atoms) × (1 mol / 6.022×1023 atoms) = 0.00807 mol
n(Mn) = (1.95×1021 atoms) × (1 mol / 6.022×1023 atoms) = 0.00324 mol
The molar mass of Co is 58.9332 g/mol
The molar mass of Rh is 102.9055 g/mol
The molar mass of Mn is 54.938 g/mol
Hence,
m(Co) = (0.00324 mol Co) × (58.9332 g Co / 1 mol Co) = 0.19094 g Co
m(Rh) = (0.00807 mol Rh) × (102.9055 g Rh / 1 mol Rh) = 0.83045 g Rh
m(Mn) = (0.00324 mol Mn) × (54.938 g Mn / 1 mol Mn) = 0.17799 g Mn
The mass of a sample = m(Co) + m(Rh) + m(Mn)
The mass of a sample = 0.19094 g + 0.83045 g + 0.17799 g = 1.19938 g = 1.2 g
The mass of a sample = 1.2 g
Answer: The mass of a sample of this alloy is 1.2 g
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