Ethyne gas combusts with oxygen gas according to the following reaction:
Calculate the volume, in mL of CO2 produced when 84.4 g of C2H2 react at 62.2 °C and 1.38 atm. (R = 0.0821 L atm/mol K)
2𝐶2𝐻2(𝑔)+5𝑂2(𝑔)⟶4𝐶𝑂2(𝑔)+𝐻2𝑂(𝑙)
(round to hundredth place)
Solution:
Balanced chemical equation:
2C2H2(g) + 5O2(g) → 4CO2(g) + 2H2O(l)
According to the equation above: n(C2H2) = n(CO2)/2
The molar mass of C2H2 is 26.04 g/mol.
Therefore,
(84.4 g C2H2) × (1 mol C2H2 / 26.04 g C2H2) = 3.24 mol C2H2
n(CO2) = 2 × n(C2H2) = 2 × 3.24 mol = 6.48 mol
According to the ideal gas law: PV = nRT
P = 1.38 atm
V = unknown
n = 6.48 mol
R = 0.0821 L atm mol-1 K-1
T = 62.2°C + 273.15 = 335.35 K
Therefore,
V = nRT/P
V(CO2) = (6.48 mol × 0.0821 L atm mol-1 K-1 × 335.35 K) / (1.38 atm) = 129.28 L = 129281.80 mL
V(CO2) = 129281.80 mL
Answer: 129281.80 mL of CO2 produced.
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