A 0.835 sample of hydrated calcium nitrate was heated carefully it has changed completely to the anhydrous form. After heating, the sample mass was recorded as 0.580g. Determine the value of x(must be a whole number)
Solution:
anhydrous form of calcium nitrate = Ca(NO3)2 (0.580 g)
hydrated calcium nitrate = Ca(NO3)2 ∙ xH2O (0.835 g)
Therefore,
Mass of xH2O = 0.835Â g - 0.580 g = 0.255 g
The molar mass of Ca(NO3)2 is 164.088 g/mol
Therefore,
Moles of Ca(NO3)2 = [0.580 g Ca(NO3)2] × [1 mol Ca(NO3)2 / 164.088 g Ca(NO3)2] = 0.00353 mol
Moles of Ca(NO3)2 = 0.00353 mol
The molar mass of H2O is 18.0153 g/mol
Therefore,
Moles of H2O = [0.255 g H2O] × [1 mol H2O / 18.0153 g H2O] = 0.01415 mol
Moles of H2O = 0.01415 mol
Ca(NO3)2: 0.00353 / 0.00353 = 1
H2O: 0.01415 / 0.00353 = 4
Thus,
The value of x is 4.
Ca(NO3)2 ∙ xH2O = Ca(NO3)2 ∙ 4H2O
Answer: The value of x is 4
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