Calculate the concentration of H, OH and pH and pOH of an aqueous solution of calcium hydroxide with a concentration of 0.005 mol / dm3 assuming complete dissociation
Solution:
calcium hydroxid - Ca(OH)2
Dissociation equation for Ca(OH)2:
Ca(OH)2 → Ca2+ + 2OH-
According to the equation above: CM[Ca(OH)2] = [OH-]/2
[OH-] = 2 × CM[Ca(OH)2] = 2 × 0.005 M = 0.01 M
[OH-] = 0.01 M
We can convert between [OH-] and pOH using the following equation:
pOH = - log[OH-]
pOH = - log(0.01) = 2
pOH = 2
For any aqueous solution at 25∘C:
pH + pOH = 14
pH = 14 - pOH = 14 - 2 = 12
pH = 12
We can convert between pH and [H+] using the following equation:
pH = - log[H+]
[H+] = 10-pH = 1×10-12 M
[H+] = 1×10-12 M
Answer:
[H+] = 1×10-12 M;
[OH-] = 0.01 M;
pH = 12;
pOH = 2.
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