The iron in an organometallic compound was determined by treating a 0.5324 g sample with HNO3 and heating to volatilize the organic material. After ignition, the residue of Fe2O3 weighed 0.1982 g.What is the %w/w Fe in this compound?
Solution:
The molar mass of Fe is 55.845 g/mol
The molar mass of Fe2O3 is 159.69 g/mol
2Fe → Fe2O3
Mass of Fe = (0.1982 g Fe2O3) × (55.845 g Fe / 159.69 g Fe2O3) × (2/1) = 0.1386 g Fe
The %w/w Fe in the sample, therefore, is
%Fe = (0.1386 g Fe / 0.5324 g sample) × 100% = 26.033%
%Fe = 26.033%
Answer: The %w/w Fe in the compound is 26.033%.
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