The two tubes each contain N2O gas (P = 4.92 atm, V = 3 L, T = 300 K) and NH3 gas (P = 2.46 atm, V = 3L, T = 300 K). After the reaction is complete, the measured volume of nitrogen gas is under conditions where 3.2 grams of oxygen gas with a volume of 5 liters is
3N2O + 2NH3 = 4N2 + 3H2O
pV = nRT
n = pV/RT
R = 0.082 L⋅atm⋅K−1⋅mol−1
n (N2O) = (4.92 x 3) / (0.082 x 300) = 0.6 mol
n (NH3) = (2.46 x 3) / (0.082 x 300) = 0.3 mol
NH3 is the limiting reagent in this reaction. Therefore:
n (N2) = 2 x n (NH3) = 2 x 0.3 = 0.6 mol
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