What will 628 mg of Zr (HPO4)2 weighed after ignition to ZrP2O7?
Solution:
Zr(HPO4)2 → ZrP2O7 + H2O
Analyte - Zr(HPO4)2; Precipitate - ZrP2O7
The molar mass of Zr(HPO4)2 is 283.1826 g/mol.
The molar mass of ZrP2O7 is 265.1673 g/mol.
Zr(HPO4)2 → ZrP2O7
Hence,
GF = (283.1826 g Zr(HPO4)2 mol-1) / 265.1673 g ZrP2O7 mol-1) × (1/1) = 1.06794 g Zr(HPO4)2 / g ZrP2O7
Gravimetric factor (GF) = 1.06794 g Zr(HPO4)2 / g ZrP2O7
grams analyte = GF × grams precipitate
Hence,
628 mg of Zr(HPO4)2 = (1.06794 g Zr(HPO4)2 / g ZrP2O7) × grams of ZrP2O7
grams of ZrP2O7 = 628 mg / 1.06794 = 588.048 mg = 588 mg ZrP2O7
Answer: 588 mg
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