A 22.11 g sample of liquid nitrogen (N2) starts at a temperature of -288 oC. How much energy is required to heat it to its boiling point of -196 oC and boil it completely?
s = 1.04 J/goC delta Hv = 2.79 kJ/mol
Solution:
The molar mass of N2 is 28.013 g/mol.
Hence,
Moles of N2 = (22.11 g N2) × (1 mol N2 / 28.013 g N2) = 0.789 mol N2
n(N2) = 0.789 mol
This problem can be summarized thusly:
1) Sample of liquid nitrogen (N2) is heated from -288°C to -196°C.
The heat is calculated by using the specific heat of liquid nitrogen (s = 1.04 J/g°C) and the equation:
q = m × S × ΔT
q1 = 22.11 g × 1.04 J/g°C × (-196 - (-288))°C = 2115.5 J = 2.116 kJ
q1 = 2.116 kJ
2) Liquid nitrogen is vaporized at -196°C.
The heat is calculated by multiplying the moles of liquid nitrogen by the heat of vaporization (ΔHv).
q2 = n(N2) × ΔHv = 0.789 mol × 2.79 kJ/mol = 2.201 kJ
q2 = 2.201 kJ
q = q1 + q2 = 2.116 kJ + 2.201 kJ = 4.317 kJ = 4.32 kJ
q = 4.32 kJ
Answer: 4.32 kJ of energy is required.
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