Solve the following problem
1. A gas occupies a volume of 500 cm 3 at 27⁰C. What will be the volume of the gas when
the temperature is -48⁰C? Assume pressure and moles are constant.
2. The pressure in an automobile tire is 29.8 psi on a cold morning of 20°C. After it is
driven a while, the temperature rises to 43°C. What is the pressure in the tire assuming
that the volume remains constant?
Solution:
Question 1:
T1 = 27°C + 273 = 300 K
V1 = 500 cm3
T2 = -48°C + 273 = 225 K
V2 = unknown
P1 = P2 = const
n1 = n2 = const
Since the pressure and amount of gas remain unchanged, Charles' Law can be used.
Charles' Law can be expressed as: V1 / T1 = V2 / T2
V1T2 = V2T1
To find the volume, solve the equation for V2:
V2 = V1T2 / T1
V2 = (500 cm3 × 225 K) / (300 K) = 375 cm3
V2 = 375 cm3
Answer to Question 1: The volume of the gas will be 375 cm3.
Question 2:
P1 = 29.8 psi
T1 = 20°C + 273 = 293 K
P2 = unknown
T2 = 43°C + 273 = 316 K
V1 = V2 = const
n1 = n2 = const
Since the volume and amount of gas remain unchanged, Gay-Lussac's Law can be used.
Gay-Lussac's Law can be expressed as: P1 / T1 = P2 / T2
P1T2 = P2T1
To find the pressure, solve the equation for P2:
P2 = P1T2 / T1
P2 = (29.8 psi × 316 K) / (293 K) = 32.14 psi
P2 = 32.14 psi
Answer to Question 2: The pressure in the tire will be 32.14 psi.
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