. At a pressure of 1.5 atm and 42.2 °C, a certain gas has a volume of 340.0 mL. What will be the volume of this gas under STP.
Solution:
STP conditions (a temperature of 273.15 K and a pressure of 1 atm).
Hence,
P1 = 1.5 atm
V1 = 340.0 mL
T1 = 42.2°C + 273.15 = 315.35 K
P2 = 1.0 atm
V2 = unknown
T2 = 273.15 K
The Combined Gas Law can be used:
P1V1/T1 = P2V2/T2
Cross-multiply to clear the fractions:
P1V1T2 = P2V2T1
Divide to isolate V2:
V2 = (P1V1T2) / (P2T1)
Plug in the numbers and solve for V2:
V2 = (1.5 atm × 340.0 mL × 273.15 K) / (1.0 atm × 315.35 K) = 441.75 mL = 441.8 mL
V2 = 441.8 mL
Answer: The volume of this gas will be 441.8 mL.
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