A 27.98 g sample of aluminum is heated from 25 oC to its melting point of 660 oC and then melted completely. How much energy was absorbed by the sample? (Answer in kJ)
S=0.91 J/goC Delta Hf = 10.7 kJ/mol
Solution:
The molar mass of Al is 26.981 g/mol.
Hence,
(27.98 g Al) × (1 mol Al / 26.981 g Al) = 1.037 mol Al
Moles of Al = 1.037 mol
This problem can be summarized thusly:
1) A sample of aluminum is heated from 25°C to 660°C. The heat absorbed is calculated by using the specific heat of aluminum (S = 0.91 J/g°C) and the equation: q = m × S × ΔT.
q1 = m × S × (Tf - Ti)
q1 = 27.98 g × 0.91 J/g°C × (660 - 25)°C = 16168.243 J = 16.168 kJ
q1 = 16.168 kJ
2) A sample of aluminum is melted at 660°C. The heat absorbed is calculated by multiplying the moles of aluminum by the molar heat of fusion (ΔHf).
q2 = ΔHf × n = 10.7 kJ/mol × 1.037 mol = 11.096 kJ
q2 = 11.096 kJ
q = q1 + q2 = 16.168 kJ + 11.096 kJ = 27.264 kJ = 27.26 kJ
q = 27.26 kJ
Answer: 27.26 kJ of energy was absorbed by the sample.
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