Liquid octane CH3CH26CH3 will react with gaseous oxygen O2 to produce gaseous carbon dioxide CO2 and gaseous water H2O. Suppose 90. g of octane is mixed with 145. g of oxygen. Calculate the maximum mass of water that could be produced by the chemical reaction. Be sure your answer has the correct number of significant digits.
CH3CH26CH3 + 11O2 = 3CO2 + 16H2O
M (CH3CH26CH3) = 68.2862 g/mol
M (O2) = 32 g/mol
M (H2O) = 18 g/mol
n = m / M
n (CH3CH26CH3) = 90 / 68.2862 = 1.32 mol
n (O2) = 145 / 32 = 4.53 mol
According to the equation, 1 mole of octane requires 11 moles of O2. Respectively, 1.32 moles of octane require 1.32 x 11 = 14.52 moles of O2.
Therefore, in this case, O2 is the limiting reactant. With all the available O2 being used, the amount of water to be produced is:
n (H2O) =n (O2) / 11 x 16 = 4.53 / 11 x 16 = 6.59 mol
m (H2O) = n x M = 6.59 x 18 = 118.6 g
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