How many milliliters (ml) of 1 M MgSO4 must be added to 50 ml of a 0.1 M MgSO4 solution to produce 1000 ml with a final MgSO4 concentration = 0.75 M? How much water?
Total number of moles of the final solution equals:
n(total) = V(final) × M(final) = 1,000 mL × 0.75 M = 1L × 0.75 M = 0.75 mol
The initial solution contains:
n(initial) = V(initial) × M(initial) = 50 mL × 0.1 M = 0.05 L × 0.1 M = 0.005 mol
From here, the number of moles of the solute that must be added is:
n(added) = n(final) - n(initial) = 0.75 mol - 0.005 mol = 0.745 mol
As a result, the volume of 1M solution to be added equals:
V(added) = n(added) / M(added) = 0.745 mol / 1M = 0.745 L = 745 mL
Finally, the volume of water that must be added equals:
V(water) = 1 L - 0.005 L - 0.745 L = 0.25 L = 250 mL
Answer: 745 mL of 1M solution and 250 mL of water
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