If 5.0 g of KClO3 are decomposed, what volume of O2 is produced at STP?
Solution:
The balanced chemical equation:
2KClO3 → 2KCl + 3O2
According to the equation above: n(KClO3) / 2 = n(O2) / 3
Moles of KClO3 = Mass of KClO3 / Molar mass of KClO3
The molar mass of KClO3 is 122.55 g mol-1.
Hence,
n(KClO3) = (5.0 g) / (122.55 g mol-1) = 0.0408 mol
n(O2) = 3 × n(KClO3) / 2 = (3 × 0.0408 mol) / 2 = 0.0612 mol (according to the equation)
At STP, one mole of any gas occupies a volume of 22.4 L.
Thus 0.0612 mol of O2 occupies:
(0.0612 mol × 22.4 L) / 1 mol = 1.37088 L of O2 = 1.37 L of O2
At STP, 0.0612 mol of O2 occupies a volume equal to 1.37 L.
OR (according to the equation):
(5.0 g KClO3)×(1 mol KClO3 / 122.55 g KClO3)×(3 mol O2 / 2 mol KClO3)×(22.4 L O2 / 1 mol O2) = 1.37 L
1.37 L O2
Answer: 1.37 liters of O2 is produced at STP.
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