Determine the vapor pressure of 20 degrees celsius of a cane sugar solution C12H22O11 containing 10 g of sugar and 100 g of water.
Solution:
The vapor pressure of pure water is 17.5 torr at 20.0 °C
(http://www.wiredchemist.com/chemistry/data/vapor-pressure).
Determine moles of water and sugar:
100 g water × (1 mol water / 18.0153 g water) = 5.5508 mol water
10 g sugar × (1 mol sugar / 342.3 g sugar) = 0.0292 mol sugar
Determine the mole fraction of the solvent (H2O):
χsolvent = mol water / (mol water + mol sugar)
χsolvent = 5.5508 mol / (5.5508 mol + 0.0292 mol) = 0.99477
χsolvent = 0.99477
Using Raoult's Law, determine the vapor pressure:
Psolution = χsolvent × P°solvent
Psolution = 0.99477 × 17.5 torr = 17.408 torr = 17.4 torr
Psolution = 17.4 torr
Answer: The vapor pressure (Psolution) of a cane sugar solution is 17.4 torr.
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