Calculate normality and titre of KOH -solution (volume 6.5 ml) if it is
nessesary for the titration 5.0 ml HCl – solution with CN = 0.1065 mol/l.
Solution:
The balanced chemical equation:
KOH + HCl → KCl + H2O
According to the equation above:
n(KOH) = n(HCl)
or
CN(KOH) × V(KOH) = CN(HCl) × V(HCl)
Hence,
CN(KOH) = CN(HCl) × V(HCl) / V(KOH)
CN(KOH) = 0.1065 mol L-1 × 5.0 mL / 6.5 mL = 0.08192 mol L-1
CN(KOH) = 0.08192 mol/L
T(KOH) = CN(KOH) × M(KOH) / 1000
The molar mass of KOH is 56.1056 g mol-1.
Hence,
T(KOH) = (0.08192 mol L-1 × 56.1056 g mol-1) / 1000 = 0.004596 g mL-1
T(KOH) = 0.004596 g/mL
Answer:
Normality of KOH solution is 0.08192 mol/L.
Titre of KOH solution is 0.004596 g/mL.
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