Calculate the molar concentration of hydrogen ions in solution: (a) pH = 2.8 and (b) pOH = 4.2?
[H+] is the molar hydrogen ion concentration (in mol L-1 or M).
Solution:
(a):
pH is defined as the negative logarithm of the hydrogen ion concentration:
pH = -log[H+]
Hence, [H+] can be calculated using the above equation:
[H+] = 10-pH
[H+] = 10-2.8 = 0.001585 M = 1.6×10-3 M
[H+] = 1.6×10-3 M
(b):
For any aqueous solution at 25∘C:
pH + pOH = 14
Hence,
pH = 14 - pOH = 14 - 4.2 = 9.8
pH is defined as the negative logarithm of the hydrogen ion concentration:
pH = -log[H+]
Hence, [H+] can be calculated using the above equation:
[H+] = 10-pH
[H+] = 10-9.8 = 1.585×10-10 M = 1.6×10-10 M
[H+] = 1.6×10-10 M
Answer:
(a): [H+] = 1.6×10-3 M
(b): [H+] = 1.6×10-10 M
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