Solution:
a) The reaction equation when solid phosphorus (V) oxide is prepared by burning solid phosphorus P4:
P4(s) + 5O2(g) → P4O10(s)
According to the equation: n(P4) = n(O2)/5 = n(P4O10)
b):
1) Moles of P4 = Mass of P4 / Molar mass of P4
The molar mass of P4 is 123.895 g mol-1.
Hence,
Moles of P4 = 1.33 g / 123.895 g mol-1 = 0.0107 mol
n(P4) = 0.0107 moles
2) Moles of O2 = Mass of O2 / Molar mass of O2
The molar mass of O2 is 15.999 g mol-1.
Hence,
Moles of O2 = 5.07 g / 15.999 g mol-1 = 0.3169 mol
n(O2) = 0.3169 moles
According to stoichiometry:
1 mol of P4 reacts with 5 mol of O2
Thus 0.0107 moles of phosphorus (P4) reacts with:
(0.0107 mol P4 × 5 mol O2) / 1 mol P4 = 0.0535 mol O2.
However, initially there is 0.3169 moles of O2 (according to the task).
Thus P4 acts as limiting reagent and O2 is excess reagent.
Therefore,
n(P4O10) = n(P4) = 0.0107 mol (according to the equation).
The molar mass of P4O10 is 283.886 g mol-1.
Mass of P4O10 = Moles of P4O10 × Molar mass of P4O10
Mass of P4O10 = 0.0107 mol × 283.886 g mol-1 = 3.0376 g = 3.04 g
Mass of P4O10 is 3.04 grams.
Answer:
a) The balanced chemical equation: P4(s) + 5O2(g) → P4O10(s)
b) 3.04 grams of P4O10 (or 0.0107 mol P4O10) can be produced.
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