For the equilibrium 2 SO3(g) ↔ 2 SO2(g) + O2(g), Kc=4.08x10-3 at 1000K. Write the equilibrium expression then solve for O2 if the equilibrium amounts are SO3(g) = 1.25M and SO2(g) = 0.0750M.
Solution:
The balanced chemical equation:
2SO3(g) ↔ 2SO2(g) + O2(g)
The equilibrium expression for the reaction system:
For [O2]:
Kc = 4.08×10-3
[SO3] = 1.25 M
[SO2] = 0.0750 M
Substitute the known equilibrium concentrations and Kc into the expression and solve for [O2]:
Answer: [O2] = 1.13 M.
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