The balanced equation for the reaction between aluminum and chlorine is written as follows:
2Al + 3Cl2 "\\rightarrow" 2AlCl3.
From this equation, one can see that 2 moles of aluminum react with 3 moles of chlorine gas and 2 moles of aluminum chloride is formed.
Let's calculate the number of the moles of aluminum and of chlorine gas available for reaction:
"n(Al) = \\frac{m}{M} = \\frac{34 \\text{ g}}{26.98 \\text{ g\/mol}} = 1.26" mol, and
"n(Cl_2) = \\frac{m}{M} = \\frac{39 \\text{ g}}{70.91 \\text{ g\/mol}} =0.550" mol.
If we analyze the stoichiometry of the reaction, we must compare the number of the moles of aluminum and that of chlorine in the following way:
"\\frac{n(Al)}{2} = 0.630"
"\\frac{n(Cl_2)}{3} = 0.183" .
As one can see from these relations, 0.630>0.183, so aluminum is in excess. Therefore, the number of the moles of AlCl3 produced must be calculated from the number of the moles of chlorine available for reaction:
"n(AlCl_3) = 2\u00b7\\frac{n(Cl_2)}{3} = 0.367" mol.
Finally, the mass of AlCl3 ("M = 133.34" g/mol) produced is:
"m(AlCl_3) = nM = 0.367\\text{ mol}\u00b7133.34\\text{ g\/mol}"
"m(AlCl_3) = 48.9" g.
Answer: if there are 34.0 g of aluminum that is reacted to 39.0 g of chlorine gas, the mass of AlCl3 is 48.9 g.
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