Sulfuric acid is needed in in a lead storage battery. A 25.00 mL sample of “battery acid” taken from the functioning battery requires 53.7 mL of 4.552 M NaOH for complete neutralization. What is the molarity of the battery acid?
Molarity of the battery acid = CM(H2SO4) = unknown
Volume of battery acid = V(H2SO4) = 25.00 mL
Molarity of sodium hydroxide = CM(NaOH) = 4.552 M
Volume of sodium hydroxide = V(NaOH) = 53.70 mL
Solution:
The reaction between sulfuric acid (H2SO4) and sodium hydroxide (NaOH) is:
H2SO4 + 2NaOH = Na2SO4 + 2H2O
According to the equation: n(H2SO4) = n(NaOH)/2
Therefore,
2 × CM(H2SO4) × V(H2SO4) = CM(NaOH) × V(NaOH)
2 × CM(H2SO4) × (25.00 mL) = (4.552 M) × (53.70 mL)
CM(H2SO4) = (4.552 M × 53.70 mL) / (2 × 25.00 mL) = 4.8888 M = 4.889 M
Molarity of the battery acid = CM(H2SO4) = 4.889 M.
Answer: The molarity of the battery acid is 4.889 M.
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