The explosion and burning of methane with oxygen results in the formation of carbon dioxide and water according to the following reaction:
CH4 + 2O2 = CO2 + 2H2O
Next, the number of moles of methane and oxygen must by calculated. As 1 mol of gas occupies 22.4 L at standard conditions, the numbers of moles of methane and oxygen are:
n(CH4) = V(CH4) / 22.4 L = 20 cm3 / 22.4 L = 0.02 L / 22.4 L = 8.9 × 10-4 mol
n(O2) = V(O2) / 22.4 L = 18 cm3 / 22.4 L = 0.018 L / 22.4 L = 8.04 × 10-4 mol
As n(O2) < n(CH4), oxygen is a limiting reagent. As a result, it must be used to calculate the number of moles of carbon dioxide produced during the reaction. As 1 mole of CO2 can be produced from two moles of oxygen:
n(CO2) = n(O2) / 2 = 8.04 × 10-4 mol / 2 = 4.02 × 10-4 mol
Finally, as 1 mol of gas occupies 22.4 L, carbon dioxide occupies:
V(CO2) = n(CO2) × 22.4 L = 4.02 × 10-4 mol × 22.4 L = 9 × 10-3 L = 9 cm3
Answer: 9 × 10-3 L or 9 cm3
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