Question #119772
Good day,
What is the half-life of a first-order reaction with a rate constant of 4.30×10−4 s−1?
1
Expert's answer
2020-06-04T10:38:47-0400

For the first-order chemical reaction A\rightarrow products, the rate law is:

[A]=[A]0ekt[A] = [A]_0e^{-kt} ,

where kk is the rate constant and tt is the time.

The half-life of a chemical reaction is the time that it takes to decrease the concentration of the reagent A by a factor of two:

[A][A]0=0.5=ekt1/2\frac{[A]}{[A]_0} = 0.5 = e^{-kt_{1/2}} .

Therefore, the half-life of the reaction is:

t1/2=ln2k=ln24.30104=1612t_{1/2} = \frac{\text{ln2}}{k} = \frac{\text{ln2}}{4.30·10^{-4}} = 1612 s.

Answer: 1612 s.


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