Question #107827

24.3 grams of a metal was heated to 95.0°C and placed immediately into an insulated container containing 50.0 grams of water at 25.0°C. The final temperature of the water is 26.8 °C. What is the specific heat of the metal?

Expert's answer

As the container is insulated, the quantity of heat that metal lost is equal to the quantity of heat received by water:

Qm=QwQ_m = -Q_w

The quantity of heat transferred to water is related to its change in temperature as follows:

Qw=cwmw(TfinTinit,w)Q_w = c_wm_w(T_{fin} - T_{init, w}) ,

where cwc_w is the specific heat of water, mwm_w is the mass of water and (TfinTinit,w)(T_{fin} - T_{init, w}) is the change in temperature. We can write an analogical expression for the metal:

Qm=cmmm(TfinTinit,m)Q_m = c_mm_m(T_{fin} - T_{init, m})

Let's join the last two equations and write the expression for the specific heat of the metal:

cwmw(TfinTinit,w)=cmmm(TfinTinit,m)c_wm_w(T_{fin} - T_{init, w}) = - c_mm_m(T_{fin} - T_{init, m})

cm=cwmw(TfinTinit,w)mm(TfinTinit,m)c_m = -\frac{c_wm_w(T_{fin} - T_{init, w})}{m_m(T_{fin} - T_{init, m})}

The specific heat of water is 4.186 J/g/°C. As you can see, we don't need to convert the temperature in kelvin here, as we use difference temperature. Finally, the specific heat of the metal is:

cm=4.18650.0(26.825.0)24.3(26.895.0)=0.227c_m = -\frac{4.186\cdot 50.0\cdot (26.8 - 25.0)}{24.3\cdot(26.8 - 95.0)} = 0.227 J/g/°C

Answer: The specific heat of the metal is 0.227 J/g/°C. With a big probability, this metal was tin.


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