Question #103643

Q. Write the chemical equation of the two methods of obtaining ethanol with the help of the Griginard reagent, and the chemical equation of the two axes of making diethyl ether from ethyl O alcohol.

Expert's answer

Solution.

1)

HC(=O)H+RMgX+H2O=CH3CH2OHH-C(=O)-H + R-MgX + H2O = CH3CH2OH

CH2(O)CH2+RMgX+H2O=CH3CH2OHCH2-(O)-CH2 + R-MgX + H2O = CH3CH2OH

2)

C2H5OH+H2SO4=C2H5OSO3H+H2OC2H5OH + H2SO4 = C2H5-O-SO3H + H2O

C2H5OH+C2H5OSO3H=C2H5OC2H5+H2SO4C2H5OH + C2H5-O-SO3H = C2H5-O-C2H5 + H2SO4

Answer:

1)

HC(=O)H+RMgX+H2O=CH3CH2OHH-C(=O)-H + R-MgX + H2O = CH3CH2OH

CH2(O)CH2+RMgX+H2O=CH3CH2OHCH2-(O)-CH2 + R-MgX + H2O = CH3CH2OH

2)

C2H5OH+H2SO4=C2H5OSO3H+H2OC2H5OH + H2SO4 = C2H5-O-SO3H + H2O

C2H5OH+C2H5OSO3H=C2H5OC2H5+H2SO4C2H5OH + C2H5-O-SO3H = C2H5-O-C2H5 + H2SO4


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