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List three trace elements that are concentrated in the Earth's crust relative to the mantle, and explain why.      

An experimenter places 15.0 mmol of A and 18.0 mmol of B in a container. The container is heated to

600 K, and the gas-phase equilibrium A + B ↔ 2C + 3D is established. The equilibrium mixture is found to

have pressure 1085 torr and to contain 10.0 mmol of C. Calculate Kp

θ

and ∆G

θ

at 600 K, assuming ideal


gas.


How long would it take (in seconds) to replace all of the hydrogen gas in a fuel cell that can accommodate 4.8 kg of hydrogen (H2). If the current supplied to the cell is 10,000 A? 

½ O2 + 2H+ + 2e- → H2O         E0 = +1.23 V

2 H+ + 2 e- → H2                               E0 = 0.00 V

F = 96,500 C/mol


an element has 2 isotopes 90% of threisotopes has a mass number of 20AMU, the other 22 mmHg, calculate the above mass of the element?

. If the standard voltage of the reaction of Cu(s) with Ag+(aq) in the question above is +0.46V, what is the standard free energy change, DGo, for the reaction?



Determine whether the statement is true or false, and why. “If a theory becomes supported by evidence, it can become a law.”


For a molecule of oxygen at 1atm pressure at 25degree Celsius
Find translational partition function

 Two excited states of the C2 molecule have the valence electron configurations below.

Assign to each all the possible term symbols: [8]

i) 1𝜎21𝜎21𝜋31𝜋1 and 𝑔𝑢𝑢𝑔

ii) 1𝜎21𝜎21𝜋21𝜋2 𝑔𝑢𝑢𝑔



Find the number of electrons exchanged in the half reaction where permanganate ion is converted to manganous ion,ieMn(ll) in acidic medium.

What volume of 1.5N NaOH is needed to react with 25ml 4.0N HCl?


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