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Give various experimental methods of rate studies
How can you determine the solubility product constant of a sparingly soluble salt using
EMF measurements?
Discuss HIttrof method for the determination of transport number
In 0.10 M solution of sodium acetate, Calculate
i) Kh
ii) the degree of hydrolysis (α)
iii) OH
iv) pH at 298K
At 298K, Kw = 1.0 × 10-14 and Ka for acetic acid = 1.8 × 10-5
State Le Chatelier’s principle. Discuss the effect of change of pressure in the synthesis of
ammonia.
Draw and explain the phase diagram of sulphur
Define osmotic pressure. Explain the laws of osmotic pressure.
State Nernst distribution law. Briefly discuss its applications
What is an ideal solution? Give two examples. When would two liquids form an ideal
solution? What are thermodynamic characteristics of ideal solution?
Write the combined mathematical statements of the first and second laws of
thermodynamics. How are these derived?
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