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a) Describe different types of electronic transitions in a molecule. Which type of
transition is responsible for a band at max = 279 nm in absorption spectrum of
acetone.
b) The dipole moment of HBr is 2.60 x 1030 C m and the interatomic distance is
141 pm. What is the percentage ionic character of HBr.
a) Explain the term dipole moment and describe briefly its experimental determination.
The inter atomic distance of 14N16O molecule is 115.1 pm. Calculate:
i) its reduced mass
ii) its moment of inertia
iii) the wave number of the line corresponding to lowest absorption in m1 unit, and
iv) the energy in m1 unit for the transition J = 2 to J = 3.
b) Write Born-Haber cycle for BaO crystal.
a) Starting from Lewis structure, determine the hybridization types of the central
atom of TeCl4 and ICl4- .
b) Explain why He2 does not exist under ordinary condition? Calculate bond order
of He2+.
a) For K+ and Br- find the radius ratio of K+ ion to Br- ion and on this basis predict the shape of crystal geometry of KBr. Draw a diagram indicating the arrangement of K+ and Br- ions in the crystal of KBr.
b) What is matter wave? What do you understand by in phase and out phase waves? Calculate the wavelength associated with a body of mass 1.5 kg moving with a velocity of 100 m s1.
a) Explain the significance of Azimuthal quantum numbers. Indicate the possible values of l and ml for n = 3.
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