Draw the Born Haber cycle for CaS( 1Mole Calcium Sulphide) inserting the appropriate energy, states of the substances and the energy values as well as their respective energy changes
Two containers, A and B, are separated by a tap. A has a volume of 15 litres and contains one mole
of helium at 25°C. B has a volume of 45 litres and is completely evacuated.
a. Calculate the change in entropy that occurs when the tap is opened.
10cm3 of 18.40M sulphuric acid was added to distilled water in a 250ml volumetric flask. The flask was stoppered, turned upside down several times and carefully topped to the mark with more distilled water. After 20minutes it was observed that the solution had dropped by 2ml from the mark.
a) How does this solution behave w.r.t. Raoult’s law? Explain your answer. b) State other observations you may note on mixing the two liquids. c) Draw a labelled vapour pressure-composition phase diagram for the solution. d) Calculate the molarity of the solution in the volumetric flask.
1a) State Raoult’s law. b) Name the components of a solution that deviates positively from Raoult’s law. c) Why does the solution in 1b deviate from ideal behavior?
Ethanal and Carbon disulphide are miscible liquid which form a two component and two phase system.
Suggest a reason why the mixture shows a positive deviation. (2 marks) d. Although the mixture cannot be separated into the two components by fractional distillation, chemical methods can be used. i. Suggest a reason why the mixture cannot be separated by fractional distillation. ii. Briefly describe chemical reactions for obtaining one of the two components from the mixture. (5marks)