Question #99477

1. Add 0.05moll-mgcl 2 solution.Can precipitation occur when ammonia water is mixed in equal volume? to 0.1mol · L-

Expert's answer

Solution.

MgCl2+2NH4OH=Mg(OH)2+2NH4ClMgCl2 + 2NH4OH = Mg(OH)2 + 2NH4Cl

Cnew(MgCl2)=C(MgCl2)2Cnew(MgCl2) = \frac{C(MgCl2)}{2}

Cnew(NH4OH)=C(NH4OH)2Cnew(NH4OH) = \frac{C(NH4OH)}{2}

Ksp=(0.025)×(0.05)2=6.25×105Ksp = (0.025)\times(0.05)^2 = 6.25 \times 10^{-5}

Ksp(theor.)=6.0×1010Ksp(theor.) = 6.0\times10^{-10}

Since the theoretical product of the solubility of magnesium hydroxide was less than the experimental one, the precipitate will fall out.

Answer:

Since the theoretical product of the solubility of magnesium hydroxide was less than the experimental one, the precipitate will fall out.

Ksp=6.25×105Ksp = 6.25 \times 10^{-5}


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