Tc=8a27RbT_c=\frac{8a}{27Rb}Tc=27Rb8a
Pc=a27b2P_c=\frac{a}{27b^2}Pc=27b2a
Hence, using Pc×Vc=R×TcP_c\times V_c=R\times T_cPc×Vc=R×Tc
Critical volume Vc=3bV_c=3bVc=3b
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