Is is related to stoichiometry of a reaction.
Let us solve it by an example:
"6CO_2+6H_2O\\to C_6H_{12}O_6+6O_2"
Molar ratio is the proportion of reactants used which can be derived from stoichiometry of a reaction.
In this case ,molar ratio is "6:6:1" for "CO_2:H_2O:glucose"
Hence by determining the molar ratio,we can determine the mass of glucose to be formed by using the proportion.
And the theoretical determined mass of glucose is theoretical mass of a product in the reaction by multiplying the ratio with their molar mass.
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