Solution:
The reversible adiabatic process for an ideal gas is described by the Poisson equation. Since the temperature is variable in the adiabatic process, the Boyle – Mariotte law requires an amendment, which Poisson designated as the coefficient k and expressed through the heat capacity ratio. For non-relativistic non-degenerate monatomic ideal k = 5/3, for diatomic k = 7 / 5.
c) Tm >Td >Ti