Answer to Question #326061 in Physical Chemistry for Angela Caliso

Question

The reaction between solid white phosphorus and oxygen produces solid

tetraphosphorusdecoxide (P4010).

a. Write the balanced chemical equation of the reaction

b. Determine the mass of tetraphosphorusdecoxide (P4010) formed if 26.0 g of

phosphorus (Pd) and 49.5 g of oxygen (O2) are combined.

c. How much of the excess reactant remains after the reaction stops?

Answer 1

P4 + 5O2 = P4O10

m(P4) = 26.0 g;

M(P4) = 124 g/mol;

n(P4) = m(P4)/M(P4) = 26.0/124 = 0.21 mol;

m(O2) = 49.5 g;

M(O2) = 32 g/mol;

n(O2) = m(O2)/M(O2) = 49.5/32 = 1.55 mol.

By the chemical reaction:

n(P4)' = n(P4) = 0.21 mol;

n(O2)' = n(O2)/5 = 1.55/5 = 0.31 mol;

So, P4 is the limiting reactant and O2 is the excess reactant.

n(P4P10) = n(P4) = 0.21 mol;

M(P4O10) = 284 g/mol;

m(P4O10) = n(P4O10) * M(P4O10) = 0.21 * 284 = 59.6 g.

Answer: 59.6 g